Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 92, Pages 14290-14300Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc04457f
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Funding
- Ministry of Education, Culture, Sports, Science and Technology, Japan [22225004]
- Naito Foundation
- Sumitomo Foundation
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Metal-ligand bifunctional cooperation has attracted much attention because it offers a powerful methodology to realize a number of highly efficient and selective catalysts. In this article, recent developments in the metal-ligand cooperative reactions of protic N-heterocyclic carbene (NHC) and pyrazole complexes bearing an acidic NH group at the position beta to the metal are surveyed. Protic 2-pyridylidenes as related cooperating non-innocent ligands are also described.
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