Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 27, Pages 3623-3626Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc00867g
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Funding
- 973 Program [2012CB725302]
- National Natural Science Foundation of China [21390400, 21025206, 21272180, 21302148]
- Research Fund for the Doctoral Program of Higher Education of China [20120141130002]
- Program for Changjiang Scholars and Innovative Research Team in University [IRT1030]
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The first copper-catalysed oxidative alkenylation of simple ethers to construct allylic ethers was successfully achieved. Different substituted olefins and simple ethers could be cross-coupled well to generate the corresponding alkenylation products. Notably, open-chain ethers were also found to be efficient coupling partners in this reaction. This reaction is likely to proceed via a radical process.
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