4.7 Article

Mn(III)-mediated reactions of 2-isocyanobiaryl with 1,3-dicarbonyl compounds: efficient synthesis of 6-alkylated and 6-monofluoro-alkylated phenanthridines

Journal

CHEMICAL COMMUNICATIONS
Volume 50, Issue 85, Pages 12892-12895

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc05324a

Keywords

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Funding

  1. Natural Science Foundation of China [21172162, 21372174]
  2. Young National Natural Science Foundation of China [21202111]
  3. PhD Programs Foundation of Ministry of Education of China [2013201130004]
  4. Young Natural Science Foundation of Jiangsu Province [BK2012174]
  5. Key Laboratory of Organic Synthesis of Jiangsu Province [KJS1211]
  6. PAPD
  7. Soochow University

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Mn(III)-mediated reactions of 2-isocyanobiaryls with 1,3-dicarbonyl compounds were described for the construction of 6-alkylated and 6-monofluoro-alkylated phenanthridines in moderate to good yields. The reaction involves formation of two new C-C bonds and one C-C bond cleavage.

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