Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 65, Pages 9179-9181Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc03304c
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Funding
- National Natural Science Foundation of China [21272028, 21202013]
- Innovation & Entrepreneurship Talents Introduction Plan of Jiangsu Province
- Natural Science Foundation of Zhejiang Province [R4110294]
- State Key Laboratory of Coordination Chemistry of Nanjing University
- Jiangsu Key Laboratory of Advanced Catalytic Materials Technology
- Jiangsu Province Key Laboratory of Fine Petrochemical Engineering
- Priority Academic Program Development of Jiangsu Higher Education Institutions
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The benzoyl peroxide (BPO)-promoted phenanthridinylation of simple alkanes with isonitrile is developed via C(sp(3))-H and C(sp(2))-H bond cleavage. This procedure is featured by dual C-C bond formation proceeding with the addition of an alkyl radical to isonitrile followed by radical aromatic cyclization.
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