Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 53, Pages 7007-7010Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc02103g
Keywords
-
Categories
Funding
- NSERC of Canada
- Canada Research Chair
Ask authors/readers for more resources
Phosphine is shown to catalyse the reaction of CO2 with 9-BBN to give mixtures of HCO2(B(C8H14)) 3, H2C(OB(C8H14))(2) 4 and MeOB(C8H14) 5; at 0.02 mol% of tBu(3)P 5 is obtained in 98% yield at 60 degrees C with TON of almost 5500 and a TOF of 170. Under stoichiometric conditions the species (R3PCH2O)(HC(O)O)B(C8H14) (R = tBu 1,4-MeC6H4 2) were isolated and characterized.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available
Share Paper
