4.7 Article

Pt nanoparticles entrapped in titanate nanotubes (TNT) for phenol hydrogenation: the confinement effect of TNT

Journal

CHEMICAL COMMUNICATIONS
Volume 50, Issue 21, Pages 2794-2796

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc49331h

Keywords

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Funding

  1. National Scientific Foundation of China [21303210]
  2. Postdoctoral Foundation of China [2013M531881]
  3. National 973 Project of China [2009CB220002]

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A Pt@TNT catalyst with Pt nanoparticles entrapped in titanate nanotubes (TNT) was prepared by hydrophobic modification of the exterior surface of the TNT and impregnation with hexachloroplatinic acid (H2PtCl6) aqueous solution. The catalyst's enhanced activity towards the hydrogenation of phenol (as high as similar to 3200 g(phenol) h(-1) g(Pt)(-1) of qTOF) can be ascribed to the confinement effect.

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