Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 96, Pages 15224-15227Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc07611g
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Funding
- 973 Program [2013CB933200, 2011CB932504]
- National Nature Science Foundation of China [21131006]
- CAS/SAFEA International Partnership Program for Creative Research Teams
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With the help of the ligand-oriented method, we have successfully embedded independent copper-based units into the indium-organic framework system for the first time, in which the Cu4I4 clusters and In3O(CO2)(6) clusters coexist. This heterometallic cluster-based framework InOF-8 has a large porosity with extra-open channels along the c-axis, and its sorption capacity has also been investigated.
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