Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 85, Pages 12923-12926Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc06851c
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Funding
- EPFL
- F. Hoffmann-La Roche Ltd
- ERC [334840]
- European Research Council (ERC) [334840] Funding Source: European Research Council (ERC)
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Highly efficient protocols for the alkynylation of H-phosphi(na)tes and secondary phosphine oxides with silyl, aryl and alkyl ethynyl-benziodoxolone (EBX) reagents are reported. Alkynyl phosphorus compounds were obtained in 69-93% yield without the need for a transition metal catalyst at room temperature under open flask conditions.
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