4.7 Article

A proton channel allows a hydrogen oxidation catalyst to operate at a moderate overpotential with water acting as a base

Journal

CHEMICAL COMMUNICATIONS
Volume 50, Issue 7, Pages 792-795

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc46829a

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Funding

  1. US Department of Energy, Early Career Research Program, Basic Energy Sciences, Chemical Sciences, Geosciences & Biosciences Division
  2. Center for Molecular Electrocatalysis, an Energy Frontier Research Center
  3. U.S. Department of Energy, Office of Science, Basic Energy Sciences

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We report the incorporation of a simple enzyme-inspired proton channel onto a hydrogen oxidation catalyst. This modification facilitates proton transfer and lowers the overpotential for oxidation of H-2 by 300 mV when using water as a base.

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