Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 72, Pages 10485-10487Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc04738a
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Funding
- DFG [NA 955/1-1]
- Fonds der Chemischen Industrie (Sachkostenzuschuss)
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An oxidative and acid-free method for the nitration of N-aryl sulfonamides has been developed using a combination of sodium nitrite as cheap and easy to handle NO2-source and the hypervalent iodine reagent PIFA as stoichiometric oxidant. Under very mild reaction conditions, the desired mononitrated aryl sulfonamides were isolated in up to 87% yield. This is the first example of an iodane-mediated oxidative nitration.
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