Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 25, Pages 3359-3362Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc49689a
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Funding
- National Natural Science Foundation of China [20772088, 21172163]
- Priority Academic Program Development of Jiangsu Higher Education Institutions
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Mn(OAc)(3)-mediated direct C-sp2-H radical trifluoromethylation of coumarins with CF3SO2Na (Langlois reagent) to afford selective 3-trifluoromethyl coumarins in moderate to good yields is described. This methodology can also be applied to the trifluoromethylation of quinolinones and pyrimidinones.
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