Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 33, Pages 4344-4346Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc00550c
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Funding
- Taiwan National Science Council [NSC: 101-2628-M-001-004-MY3]
- Academia Sinica
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Synthesis of guanidine-linked NHC can be achieved easily through reacting amino-NHC with carbodiimide. Subsequently, guanidine-NHC Ag and Cu complexes were isolated and fully characterized. These Cu complexes are found to be versatile catalysts for hydroboration, semihydrogenation and carboboration of alkynes in a highly stereo- and regioselective fashion.
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