4.7 Article

Visible-light-enhanced Suzuki-Miyaura coupling reaction by cooperative photocatalysis with an Ru-Pd bimetallic complex

Journal

CHEMICAL COMMUNICATIONS
Volume 50, Issue 93, Pages 14501-14503

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc03682d

Keywords

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Funding

  1. Ministry of Education, Culture, Sports, Science and Technology of Japan [252892890]
  2. JSPS Asian CORE Program
  3. MEXT
  4. Grants-in-Aid for Scientific Research [26620194, 26220911, 26630409] Funding Source: KAKEN

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A photo-assisted Suzuki-Miyaura coupling reaction has been realized by a molecule Pd(II) complex containing a Ru(II)-polypyridyl derivative as a visible light photosensitizing unit, where an electron transfer from excited Ru species to Pd forms an active electron rich Pd(0) and facilitates the oxidative addition step with aryl halides.

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