Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 32, Pages 4255-4257Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc49342c
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Funding
- 973 Program [2012CB821702, 2011CB935902]
- NSFC [91122004, 21271137, 81202421]
- MOE [IRT-13R30, IRT13022]
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Two unique heptanuclear clusters Ln@Zn-6 (Ln = Dy (1), Er (2)) were structurally and magnetically characterized. Each Dy3+/Er3+ is located in a nona-coordinate D-3h coordination environment, and is encapsulated in a diamagnetic Zn-6 cage. Compound 1 exhibits single-ion magnetic behavior, and is the first example of a single-ion magnet (SIM) constructed through embedding one magnetic anisotropic metal ion into a diamagnetic cage.
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