4.7 Article

A low temperature, isothermal gas-phase system for conversion of methane to methanol over Cu-ZSM-5

Journal

CHEMICAL COMMUNICATIONS
Volume 50, Issue 75, Pages 11053-11055

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc02832e

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Funding

  1. EPSRC through the CASTech project [EP/G012156/1]
  2. DEL (UK)
  3. EPSRC [EP/G012156/1] Funding Source: UKRI
  4. Engineering and Physical Sciences Research Council [EP/G012156/1] Funding Source: researchfish

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A low temperature, isothermal, gas-phase, recyclable process is described for the partial oxidation of methane to methanol over Cu-ZSM-5. Activation in NO at 150 degrees C followed by methane reaction and steam extraction (both at 150 degrees C) allowed direct observation of methanol at the reactor outlet.

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