Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 94, Pages 14775-14777Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc07378a
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Funding
- National Natural Science Foundation of China [21102104, 21272177]
- Natural Science Foundation of Zhejiang Province [LY14B020011]
- Faculty of Chemistry & Material Engineering, Wenzhou University
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A novel and convenient protocol for the formation of amides via palladium-catalyzed N-dealkylative carbonylation of alkyl tertiary amines has been developed. In the presence of PdCl2(PhCN)(2), CuO, PhCN and CO, a range of substituents on both aryl iodides and alkyl tertiary amines were compatible with the reaction to afford a series of N,N-disubstituted amides in moderate to excellent yields.
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