Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 37, Pages 4856-4859Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc00971a
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Funding
- AFOSR [FA9550-141-0014]
- DURIP [FA2386-12-1-3031, DURIP 12RSL231]
- NSF [DMR-1264801]
- Direct For Mathematical & Physical Scien [1264801] Funding Source: National Science Foundation
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H-2-C-13 HETCORMAS NMR is performed on H-2/C-13/N-15-Pro enriched A. aurantia dragline silk. Proline dynamics are extracted from H-2 NMR line shapes and T-1 in a site-specific manner to elucidate the backbone and side chain molecular dynamics for the MaSp2 GPGXX beta-turn regions for spider dragline silk in the dry and wet, super-contracted states.
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