Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 93, Pages 14609-14612Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc05898d
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- Natural Sciences and Engineering Research Council of Canada (NSERC)
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A free base porphyrin/zinc(II)porphyrin dyad bridged by a Pd(II) unit exhibits an ultrafast S-1 energy transfer (1.5 x 10(12) s(-1)) due to significant MO couplings between the acceptor and the donor and a non-nil atomic contribution of the Pd-atom in the frontier MOs, hence ensuring pi-conjugation.
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