Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 23, Pages 3052-3054Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc48481e
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Funding
- EPSRC [EP/P505178/1]
- Royal Society
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A Pd-mediated direct C-H bond functionalisation of tryptophan has been developed, both as a single amino acid residue and within peptides. Important mechanistic insight into this process has been gained by characterising a Pd catalytically competent nanoparticle phase which evolves during the early stages of reaction.
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