4.7 Article

Supramolecular copolymers obtained from two-component gels: metal ion-mediated cross-linking, enhanced viscoelasticity and supramolecular yarns

Journal

CHEMICAL COMMUNICATIONS
Volume 50, Issue 100, Pages 15874-15877

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc07813f

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Funding

  1. Basic Research Development Program [2013CB834504]
  2. National Natural Science Foundation of China [91027042, 21321063, 21227802]
  3. Strategic Priority Research Program'' of the Chinese Academy of Sciences [XDB12020200]
  4. Chinese Academy of Sciences

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The hydrogels based on the co-assembly of bolaamphiphilic L-histidine and 2,2'-bipyridine-dicarboxylic acids were transformed into viscoelastic supramolecular polymers by cross-linking with Cu(II) ions, and macroscopic supramolecular yarns were obtained by direct drawing from a dilute aqueous solution of the supramolecular polymers.

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