4.7 Article

NH3 treatment of TiO2 nanotubes: from N-doping to semimetallic conductivity

Journal

CHEMICAL COMMUNICATIONS
Volume 50, Issue 59, Pages 7960-7963

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc02069c

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Funding

  1. DFG
  2. Erlangen DFG cluster of excellence (EAM)
  3. Deanship of Scientific Research (DSR)
  4. King Abdulaziz University, Jeddah [22-130/1433HiCi]
  5. DSR

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In the present work we show that a suitable high temperature ammonia treatment allows for the conversion of single-walled TiO2 nanotube arrays not only to a N-doped photoactive anatase material (which is already well established), but even further into fully functional titanium nitride (TiN) tubular structures that exhibit semimetallic conductivity.

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