Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 99, Pages 15718-15721Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc07616h
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Funding
- Spanish Ministry of Economy and Competitiveness [CTQ2013-45011]
- Junta de Andalucia [FQM-2126]
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A stable nickel(II) methyl complex containing a diphosphino-boryl (PBP) pincer ligand is described. Mechanistic studies on the hydrogenolysis of the Ni-Me bond suggest a metal ligand cooperation mechanism that involves the intermediacy of a sigma-B-H Ni(0) species that further undergoes B-H oxidative addition to form a Ni(II) hydride complex.
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