4.7 Article

A highly efficient Pd-catalyzed decarboxylative ortho-arylation of amides with aryl acylperoxides

Journal

CHEMICAL COMMUNICATIONS
Volume 50, Issue 94, Pages 14862-14865

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc06457g

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Funding

  1. National Science Foundation of China [21172092]

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An efficient Pd-catalyzed decarboxylative ortho-arylation of amides with aryl acylperoxides was developed. A variety of anilides reacted with aryl acylperoxides to afford the corresponding ortho-arylation products, and N-methoxyarylamides generated phenanthridinones.

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