4.7 Article

5,5′-Bis-(trinitromethyl)-3,3′-bi-(1,2,4-oxadiazole): a stable ternary CNO-compound with high density

Journal

CHEMICAL COMMUNICATIONS
Volume 50, Issue 18, Pages 2268-2270

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc49879d

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Funding

  1. Ludwig-Maximilian University of Munich (LMU)
  2. U.S. Army Research Laboratory (ARL) [W911NF-09-2-0018]
  3. Armament Research, Development and Engineering Center (ARDEC) [W911NF-12-1-0467, W911NF-12-1-0468]
  4. Office of Naval Research (ONR) [ONR.N00014-10-1-0535, ONR.N00014-12-1-0538]

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5,5'-Bis-(trinitromethyl)-3,3'-bi-(1,2,4-oxadiazole) is a new ternary CNO-compound. It has been synthesized by nitration of diammonium 5,5'-bis-(dinitromethanide)-3,3'-bi-(1,2,4-oxadiazole) with nitronium tetrafluoroborate. Single crystal X-ray diffraction studies show a remarkable high density. Thermal stability and sensitivities of the new compound were determined by differential scanning calorimetry (DSC) and standardized drop hammer and friction tests.

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