4.7 Article

A proton-conducting lanthanide metal-organic framework integrated with a dielectric anomaly and second-order nonlinear optical effect

Journal

CHEMICAL COMMUNICATIONS
Volume 50, Issue 49, Pages 6513-6516

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc00458b

Keywords

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Funding

  1. National Basic 25 Research Program of China (973 Program) [2012CB821700]
  2. National Natural Science Foundation of China [20831002, 20502024]
  3. China Postdoctoral Science Foundation [20100481049]
  4. Scientific Research Program from the Education Department of Shaanxi Provincial Government [2013JK0654]
  5. Priming Scientific Research Foundation [BS1115]
  6. Provincial Innovation Training Project [1399]

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A multifunctional metal-organic framework generated from chiral tricarboxylate ligands and gadolinium ions has been successfully synthesized and characterized. It shows proton conduction, dielectric anomalous behaviour and a second-order NLO effect.

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