4.7 Article

AgSbF6-controlled diastereodivergence in alkyne hydroarylation: facile access to Z- and E-alkenyl arenes

Journal

CHEMICAL COMMUNICATIONS
Volume 50, Issue 59, Pages 8028-8031

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc03602f

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Funding

  1. National Research Foundation of Korea [NRF-2011-0016436]
  2. Institute for Basic Science (IBS) in Korea
  3. Global PhD Fellowship [NRF-2011-0007511]

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AgSbF6-controlled diastereodivergent hydroarylation reactions were developed. Unprecedented and remarkable switching of the E/Z-stereoselectivity could be obtained by adjusting the AgSbF6 loading.

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