4.7 Article

Chirality-switchable circularly polarized luminescence in solution based on the solvent-dependent helix inversion of poly(quinoxaline-2,3-diyl)s

Journal

CHEMICAL COMMUNICATIONS
Volume 50, Issue 69, Pages 9951-9953

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc03944k

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Funding

  1. Japan Science and Technology Corporation (CREST, Development of High-performance Nanostructures for Process Integration Area)
  2. Ministry of Education, Culture, Sports, Science, and Technology, Japan
  3. Grants-in-Aid for Scientific Research [25410128, 14J05141] Funding Source: KAKEN

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Poly(quinoxaline-2,3-diyl)s containing (S)-2-methylbutoxy side chains were found to exhibit blue circularly polarized luminescence (CPL). The handedness of the CPL could be switched by a solvent-dependent helix inversion of the polymer backbone between chloroform (M-helical structure) and 1,1,1-trichloroethane (P-helical structure).

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