4.7 Article

Post-functionalization of graphitic carbon nitrides by grafting organic molecules: toward C-H bond oxidation using atmospheric oxygen

Journal

CHEMICAL COMMUNICATIONS
Volume 50, Issue 48, Pages 6312-6315

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc02676d

Keywords

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Funding

  1. National Natural Science Foundation of China [U1162124, 21376208]
  2. Zhejiang Provincial Natural Science Foundation for Distinguished Young Scholars of China [LR13B030001]
  3. Specialized Research Fund for the Doctoral Program of Higher Education [J20130060]
  4. Fundamental Research Funds for the Central Universities
  5. Program for Zhejiang Leading Team of ST Innovation
  6. Partner Group Program of the Zhejiang University
  7. Max-Planck Society

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Described here is the feasible modification of a graphitic carbon nitride polymer using Prato's reaction with in situ formed azomethine ylides. These novel carbon nitrides with designable organic functional groups, and tailorable surface and structure properties illustrated excellent performance in the selective oxidation of 3,5,5-trimethylcyclohex-3-en-1-one using atmospheric oxygen.

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