4.7 Article

Hydrogenase biomimetics: Fe-2(CO)(4)(mu-dppf)(mu-pdt) (dppf=1,1 '-bis(diphenylphosphino)ferrocene) both a proton-reduction and hydrogen oxidation catalyst

Journal

CHEMICAL COMMUNICATIONS
Volume 50, Issue 8, Pages 945-947

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc46456c

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Funding

  1. Commonwealth Scholarship Commission
  2. EPSRC
  3. EPSRC [EP/D070538/1] Funding Source: UKRI
  4. Engineering and Physical Sciences Research Council [EP/D070538/1] Funding Source: researchfish

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Fe-2(CO)(4)(mu-dppf)(mu-pdt) catalyses the conversion of protons and electrons into hydrogen and also the reverse reaction thus mimicing both types of binuclear hydrogenase enzymes.

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