Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 71, Pages 10241-10243Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc04370g
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Funding
- Japan Science and Technology Agency (JST)
- Ministry of Education, Culture, Sports, Science and Technology, Japan
- Grants-in-Aid for Scientific Research [25810047, 14J02981, 25620043, 26708006, 25107716] Funding Source: KAKEN
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We observed an ordered-to-disordered structural transformation in a Cu2+ coordination polymer and investigated its influence on the proton conductivity. The transformation generated highly mobile proton carriers in the structure. The resulting material exhibited a conductivity greater than 10(-2) S cm(-1) at 130 degrees C. The structural transformation and the conduction mechanism were investigated by EXAFS, TPD-MS and NMR.
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