Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 53, Pages 7056-7059Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc03218g
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- Karlsruhe Institute of Technology (KIT) in the context of the Helmholtz BIF program
- German Research Council (DFG)
- Ministry of Science and Arts of the state of Baden-Wurttemberg
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In the present communication we introduce a new platform technology for the reversible folding of single polymer chains in aqueous environment on the basis of cyclodextrin (CD) host-guest chemistry and controlled radical polymerization protocols. The single-chain folding of adamantyl-beta-CD alpha-omega-functionalized poly(N,N-dimethylacrylamide) and its reversion at elevated temperatures were monitored by DLS and nuclear Overhauser enhancement spectroscopy (NOESY).
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