4.7 Article

Supramolecular chains of high nuclearity {Mn-25(III)} barrel-like single molecule magnets

Journal

CHEMICAL COMMUNICATIONS
Volume 50, Issue 7, Pages 779-781

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc47094f

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Funding

  1. Brock University
  2. NSERC
  3. CRC
  4. CFI
  5. National Science Foundation [DMR-1213030]
  6. ERC Advanced Grant MolNanoSpin [226558]

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The first application of 1-methyl-1H-pyrrole-2-carbaldehyde oxime as a ligand for the coordination of paramagnetic transition metal ions has afforded a new {Mn-25(III)} barrel-like cluster linked via Na+ cations into a 1D polymeric topology that exhibits single-molecule magnetic behaviour.

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