4.7 Article

A fluorescent ratiometric nanosized system for the determination of PdII in water

Journal

CHEMICAL COMMUNICATIONS
Volume 50, Issue 96, Pages 15259-15262

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc07969h

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Funding

  1. Universities of Urbino, Cagliari and Bologna (FARB Project Advanced Ultrasensitive Multiplex Diagnostic Systems Based on Luminescence Techniques), Regione Autonoma della Sardegna [CRP-59699]

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The fluorescent ligand (L) based on the N2S2 pyridinophane macrocycle and the 7-nitrobenzo[1,2,5] oxadiazole (NBD) fluorogenic fragment has been synthesized to coordinate Pd-II ions. Loaded on dye-doped silica nanoparticles, L can be used as a ratiometric fluorescent chemosensor for Pd-II in water with high selectivity toward other metal ions including the platinum group ones.

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