Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 61, Pages 8420-8423Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc02098g
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Funding
- Spanish Ministerio de Economia y Competitividad [MINECO-CTQ2010-16226, CTQ2011-29054-C02-02]
- Genera Etat de Catalunya [2009SGR-00259]
- ICIQ Foundation
- Natural Sciences and Engineering Research Council of Canada
- Mount Allison University
- URV-ICIQ
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Activated olefins directly react with a phenylselenium borane, at room temperature, without any metal or organocatalytic assistance. Up to 10 examples of beta-(phenylseleno) substituted ketones and aldehydes have been prepared and theoretical evidence for the mechanism opens up non-existing pathways to create C-heteroatom bonds as a general tool
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