4.7 Article

Highly selective defect-mediated photochemical CO2 conversion over fluorite ceria under ambient conditions

Journal

CHEMICAL COMMUNICATIONS
Volume 50, Issue 16, Pages 2005-2007

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc47806h

Keywords

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Funding

  1. National Basic Research Program of China [2013CB933203, 2010CB933503]
  2. National Natural Science Foundation of China [51272269, 51272303, 51102262]

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A highly selective defect-mediated photochemical CO2 conversion to CO over defective CeO2 nanorods under ambient conditions (CO2 400 ppm) is presented. The local strain and surface oxygen vacancies embedded in the defect-rich CeO2 are suggested to play a decisive role in mediating the photochemical CO2 conversion.

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