4.7 Article

Enhanced stereoselectivity in a di-Ru(II) complex of an achiral bis-bidentate ligand

Journal

CHEMICAL COMMUNICATIONS
Volume 50, Issue 25, Pages 3303-3305

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc47856d

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Funding

  1. Natural Sciences and Engineering Research Council of Canada (NSERC)
  2. Centre for Self-Assembled Chemical Structure (CSACS)

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The diastereoselective formation of a meso-dinuclear Ru(II) complex of a novel bis-bidentate ligand is reported along with its electrochemical and photophysical properties. The design of the ligand, with its parallel coordination vectors, induces a diastereoselectivity of 1 : 13 : 1 [Lambda Lambda : (Lambda Delta or Delta Lambda) : Delta Delta] for the dinuclear complex.

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