Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 46, Pages 6145-6148Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc01822b
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Funding
- National Nature Science Foundation of China [2127222, 91213303, 21172205, J1030412]
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A highly efficient and selective reaction for the synthesis of 2-substituted benzoxazoles and benzimidazoles catalyzed by Au/TiO2 has been developed via two hydrogen-transfer processes. This reaction has a good tolerance to air and water, a wide substrate scope, and represents a new avenue for practical C-N and C-O bond formation. More importantly, no additional additives, oxidants and reductants are required for the reaction and the catalyst can be recovered and reused readily.
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