Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 94, Pages 14763-14766Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc06228k
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- German Science Foundation [AN 238/16-1]
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Homoleptic cerium(IV) diisopropylamide was synthesized via oxidation of ate complex Ce(NiPr2)(4)Li(thf) with trityl chloride or hexachloroethane. Due to its ready accessibility, and high pK(a) value of the proligand HNiPr2, Ce(NiPr2)(4) features a promising candidate for protonolysis reactions, as shown for the synthesis of dimeric cerium(IV) tetrakis(1,1,3,3-N,N,N',N'-tetramethylguanidinate).
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