4.7 Article

An efficient triazole-pyridine-bistetrazolate platform for highly luminescent lanthanide complexes

Journal

CHEMICAL COMMUNICATIONS
Volume 50, Issue 71, Pages 10323-10326

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc04060k

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Funding

  1. French Agence Nationale de la Recherche [ANR-13-BS08-0011-01]
  2. Labex Arcane [ANR-11-LABX-003-01]

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Two new triazole-pyridine-bistetrazolate ligands were synthesized via a versatile procedure that allows for further derivatization; their corresponding homoleptic tris-ligand nona-coordinated lanthanide complexes are highly luminescent in the solid state and in a PVA polymeric matrix with measured values for the luminescence quantum yield of 70(7) and 98(9)% for Eu-III and Tb-III, respectively.

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