4.7 Article

Ionic liquid derived carbons as highly efficient oxygen reduction catalysts: first elucidation of pore size distribution dependent kinetics

Journal

CHEMICAL COMMUNICATIONS
Volume 50, Issue 12, Pages 1469-1471

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc48942f

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Funding

  1. FIRST Center
  2. Energy Frontier Research Center
  3. U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences
  4. U.S. Department of Energy, Basic Energy Sciences, Materials Sciences and Engineering Division

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Metal-free N-doped carbons with controllable pore texture were derived from carbonization of ionic liquid and served as catalysts for oxygen reduction reaction (ORR) with an activity comparable to that of Pt/C. The investigation shows that both the ORR activity and kinetics are strongly correlated with the pore size distribution.

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