Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 34, Pages 4489-4491Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc00427b
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The first enantio- and chemoselective Bronsted-acid catalysed reduction of alpha-keto esters with catecholborane has been developed. The alpha-hydroxy esters were obtained under mild reaction conditions in virtually quantitative yields and excellent enantioselectivities. With slight modifications both enantiomers can be obtained without any loss of selectivity.
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