Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 62, Pages 8464-8467Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc01841a
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Funding
- National Natural Science Foundation of China [21275136]
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The electrochemical production of H2O2 from O-2 catalyzed by [Au-25(SC12H25)(18)] was studied as a function of the charge state (-1, 0 and +1). Maximum H2O2 production (similar to 90%) was obtained from the negatively charged clusters (Au-25(-)) due to the efficient electron transfer from the anionic Au-25(-) cluster into the LUMO (pi*) of O-2.
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