4.7 Article

Porous organic ligands (POLs) for synthesizing highly efficient heterogeneous catalysts

Journal

CHEMICAL COMMUNICATIONS
Volume 50, Issue 80, Pages 11844-11847

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc03884c

Keywords

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Funding

  1. NSFC [U1162201, 21333009, 21273197]
  2. National High-Tech Research and Development program of China [2013AA065301]
  3. Fundamental Research Funds for the Central Universities [2013XZZX001]

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We reported a universal route for synthesizing porous organic ligands (POLs) via solvothermal polymerization. The POLs were obtained quantitatively, showing high surface area, large pore volume, hierarchical porosity, and superior stability. The POL bearing a triphenylphosphine supported rhodium catalyst (Rh/POL-PPh3) exhibits high activity and excellent recyclability in 1-octene hydroformylation.

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