4.7 Article

Motorized Janus metal organic framework crystals

Journal

CHEMICAL COMMUNICATIONS
Volume 50, Issue 96, Pages 15175-15178

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc06952h

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Funding

  1. Institute of Materials Research and Engineering (Science and Engineering Research Council, Agency for Science, Technology and Research, Singapore)
  2. Institute of Bioengineering and Nanotechnology (Biomedical Research Council, Agency for Science, Technology and Research, Singapore)

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We describe Janus metal organic framework crystals that are propelled by bubble ejection. The Janus crystals are prepared by selective epitaxial growth of ZIF-67 on ZIF-8. The Janus crystals catalyse the decomposition of H2O2 into H2O and O-2 on the ZIF-67 surface but not on the zinc containing ZIF-8 surface, resulting in propulsion of the Janus crystals.

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