Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 91, Pages 14109-14112Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc05987e
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Funding
- National Science Foundation [CHE-1152362]
- XSEDE [TG-DMR090028]
- EU [REGPOT-2011-1]
- European Commission [283883]
- King Abdullah University of Science and Technology (KAUST)
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A combined inelastic neutron scattering (INS) and theoretical study of H-2 sorption in Y-FTZB, a recently reported metal-organic framework (MOF) with fcu topology, reveals that the strongest binding site in the MOF causes a high barrier to rotation on the sorbed H-2. This rotational barrier for H-2 is the highest yet of reported MOF materials based on physisorption.
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