Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 83, Pages 12476-12478Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc05525j
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We present a non-ionic water-soluble porphyrin that does not exhibit measurable aggregation even at high concentrations in water. The spin state of the corresponding nickel((II)) complex changes from completely diamagnetic (low-spin) to paramagnetic (high-spin) upon addition of a strong axial ligand. This leads to a strongly reduced NMR relaxation time of the water protons even at low concentrations of the complex.
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