4.7 Article

Acid-free regioselective aminocarbonylation of alkenes

Journal

CHEMICAL COMMUNICATIONS
Volume 50, Issue 58, Pages 7848-7851

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc02167c

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Funding

  1. EPFL
  2. Swiss National Science Foundation

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An efficient method for the synthesis of N-aryl monosubstituted carboxamides via the Pd-catalyzed carbonylation of alkenes with CO and amines is described. Mechanistic insights for this highly selective reaction are provided.

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