Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 74, Pages 10805-10808Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc04707a
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Funding
- NSFC [21102061, 21202073, 21290180, 21272097, 21372104]
- 973'' Program of MOST [2010CB833203]
- 111'' Program of MOE
- Project of MOST [2012ZX 09201101-003]
- fundamental research funds for the central universities [lzujbky-2014-k20]
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A novel Mn(III)/TEMPO-co-mediated tandem azidation-1,2-carbon migration reaction of allylic silyl ethers with an unactivated C=C bond has been explored, generating alpha-aryl-alkyl beta-azido ketones with an alpha-quaternary stereocenter.
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