Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 99, Pages 15692-15695Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc07892f
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Funding
- Erasmus mobility program
- AMIE (Aide a la Mobilite Internationale des E Etudiants) of the Region Ile de France
- UPMC
- Alexander-von-Humboldt Foundation
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The catalyst-free room temperature iClick reaction of an unsymmetrically 2,3-disubstituted oxanorbornadiene (OND) as a `` masked'' alkyne equivalent with [Mn(N-3)(bpy(CH3,CH3))(CO)(3)] leads to isolation of a phenylalanine ester bioconjugate, in which the model amino acid is linked to themetal moiety via a N-2-coordinated triazolate formed in a cycloaddition-retro-Diels-Alder (crDA) reaction sequence, in a novel approach to bioorthogonal coupling reactions based on metalcentered reactivity.
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