Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 88, Pages 13489-13491Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc06081d
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Funding
- NEXT program
- CREST-JST
- MEXT
- Program for Leading Graduate Schools Integrative Graduate Education and Research Program in Green Natural Sciences in Nagoya University
- Asahi Glass foundation
- JSPS for Scientific Research
- Grants-in-Aid for Scientific Research [13J07425] Funding Source: KAKEN
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Highly enantioselective protonation of a-halo and alkoxy carboxylic acid-derived ketene disilyl acetals is achieved by using P-spiro chiral diaminodioxaphosphonium barfate as a Bronsted acid catalyst, where the enantiofacial discrimination by the catalyst mainly stems from the recognition of the electronic difference between two substituents on the ketene disilyl acetal.
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